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果树所系统解析手性农药乙螨唑的立体选择性

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  日前,中国农业科学院果树研究所果品质量安全风险监测与评估创新团队从生物活性、急性毒性、环境行为等3个方面对手性农药乙螨唑的立体选择性进行了系统解析。研究结果对于乙螨唑的安全使用和风险评估等具有极其重要的理论意义和实践应用价值,并可为该类农药的安全应用和有效管理提供科学参考。相关研究成果在线发表在《农业与食品化学杂志(Journal of Agricultural and Food Chemistry)》上。

  乙螨唑是一种新型高效杀螨剂,可用于苹果、柑橘、葡萄、棉花等作物的害螨防治。然而,乙螨唑均以外消旋体的形式销售和使用。乙螨唑进入环境后,不同对映体对靶标生物的生物活性、非靶标生物的生态毒性以及其在植物和土壤中的环境行为往往存在显著差异。传统的手性农药安全风险评估通常不区分对映体之间的差异,往往导致风险评估结果不可靠,给人类健康和环境安全带来了诸多隐患。

  该研究首次系统解析了乙螨唑不同对映体在水果(苹果、草莓、葡萄)和田间土壤中的立体选择性环境行为、对靶标生物(朱砂叶螨、二斑叶螨)的生物活性和对非靶标生物(斑马鱼、大型溞)的急性毒性。研究结果表明,乙螨唑不同对映体的生物活性和急性毒性均存在显著的立体选择性,其在田间土壤和水果中存在显著的立体选择性环境行为。

  该研究得到现代农业(苹果)产业技术体系、中国农科院科技创新工程、国家果品质量安全风险评估专项等项目的资助。(通讯员 何文上)

  原文链接:https://pubs.acs.org/doi/10.1021/acs.jafc.9b01257

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